Lattice-Stiffening Transition in Copolymer Films of Vinylidene Fluoride (70%) with Trifluoroethylene (30%)

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Surface structure of ultrathin copolymer films of ferroelectric vinylidene fluoride (70%) with trifluoroethylene (30%) on graphite

The structure and local structural distortions, through the polarization manipulation, of crystalline films of ferroelectric vinylidene fluoride (70%) with trifluoroethylene (30%) [P(VDF-TrFE)] copolymer on graphite were studied by scanning tunneling microscopy (STM). A quasispiral twist in CuC bonds with rotations about the polymer chain axis was observed by high-resolution STM, indicating a s...

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Universal Ferroelectric Switching Dynamics of Vinylidene Fluoride-trifluoroethylene Copolymer Films

In this work, switching dynamics of poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] copolymer films are investigated over unprecedentedly wide ranges of temperature and electric field. Remarkably, domain switching of copolymer films obeys well the classical domain nucleation and growth model although the origin of ferroelectricity in organic ferroelectric materials inherently differs ...

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Comparison of crystalline thin poly(vinylidene (70%)â•fitrifluoroethylene (30%)) copolymer films with short chain poly(vinylidene fluoride) films

We compare the photoemission and electron energy loss spectra of crystalline poly(vinylidene-fl uoride with trifl uoroethylene: 70%: 30%), P(VDF–TrFE), fi lms, fabricated by the Langmuir–Blodgett technique and annealed in vacuum, with in situ thermally evaporated fi lms of poly(vinylidene-fl uoride) (PVDF) in vacuum. Th e electronic structure and vibrational modes of the short chain PVDF fi lms...

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ژورنال

عنوان ژورنال: Physical Review Letters

سال: 1999

ISSN: 0031-9007,1079-7114

DOI: 10.1103/physrevlett.83.4562